Chemical bonding at the metal-organic framework/metal oxide interface: Simulated epitaxial growth of MOF-5 on rutile TiO2

Thin-film deposition of metal-organic frameworks (MOFs) is now possible, but little is known regarding the microscopic nature of hybrid hetero-interfaces. We first assess optimal substrate combinations for coherent epitaxy of MOFs based on a lattice matching procedure. We then perform a detailed qua...

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Bibliographic Details
Main Authors: Bristow, J., Butler, K., Svane, K., Gale, Julian, Walsh, A.
Format: Journal Article
Published: R S C Publications 2017
Online Access:http://hdl.handle.net/20.500.11937/52439