Lewis base complexes of AlH3: Prediction of preferred structure and stoichiometry

QR Code

Lewis base complexes of AlH3: Prediction of preferred structure and stoichiometry

The structures adopted by a range of complexes AlH3·nL, (n = 1 or 2), have been explored in detail to identify the factors that determine the value of n, and whether a monomeric or dimeric arrangement is preferred for the 1 : 1 complexes. Single-crystal X-ray diffraction, vibrational and NMR spectro...

Full description

Bibliographic Details
Main Authors:	Humphries, Terry, Munroe, K., Decken, A., McGrady, G.
Format:	Journal Article
Published:	2013
Online Access:	http://hdl.handle.net/20.500.11937/4938

Similar Items

Lewis base complexes of AlH3: Structural determination of monomeric and polymeric adducts by X-ray crystallography and DFT calculations
by: Humphries, Terry, et al.
Published: (2013)

NMR spectroscopic and thermodynamic studies of the etherate and the a, a', and γ phases of AlH3
by: Humphries, Terry, et al.
Published: (2013)

A structural study of bis-(trimethylamine)alane, AlH3�2NMe3, by variable temperature X-ray crystallography and DFT calculations
by: Humphries, Terry, et al.
Published: (2009)

Characterisation of mechanochemically synthesised alane (AlH3) nanoparticles
by: Paskevicius, Mark, et al.
Published: (2009)

In situ high pressure NMR study of the direct synthesis of LiAlH 4
by: Humphries, Terry, et al.
Published: (2013)

Regeneration of LiAlH4 at sub-ambient temperatures studied by multinuclear NMR spectroscopy
by: Humphries, Terry, et al.
Published: (2017)

In situ high pressure NMR study of the direct synthesis of NaAlH 4
by: Humphries, Terry, et al.
Published: (2013)

Formation of aluminium hydride (AlH3) via the decomposition of organoaluminium and hydrogen storage properties
by: Wang, L., et al.
Published: (2017)

Temporal and spatial imaging of hydrogen storage materials: Watching solvent and hydrogen desorption from aluminium hydride by transmission electron microscopy
by: Beattie, S., et al.
Published: (2008)

Enhanced tunability of thermodynamic stability of complex hydrides by the incorporation of H- anions
by: Takagi, S., et al.
Published: (2014)

The effect of stoichiometry on the thermal behaviour of synthetic iron-nickel sulfides
by: Chamberlain, Anthony C.
Published: (1996)

Lewis Harcourt’s journal of the 1914 war crisis
by: Young, John W.
Published: (2017)

Pendekatan Ionik dalam Menulis Struktur Lewis
by: Ahmad, Wan Yaacob, et al.
Published: (1997)

Secondary school students’ understanding of attributes for solving stoichiometry problems / Norini Jaafar
by: Jaafar, Norini
Published: (2015)

Secondary school students' understanding of attributes for solving stoichiometry problems / Norini Jaafar
by: Jaafar, Norini
Published: (2015)

Structural basis of Lewis(b) antigen binding by the Helicobacter pylori adhesin BabA
by: Hage, Naim, et al.
Published: (2015)

Effect of surface Lewis acidity on selective catalytic reduction of NO by C3H6 over calcined hydrotalcite
by: Yuan, D., et al.
Published: (2013)

Complex transition metal hydrides incorporating ionic hydrogen: Thermal decomposition pathway of Na2Mg2FeH8 and Na2Mg2RuH8
by: Humphries, Terry, et al.
Published: (2015)

Students' Dilemmas in Reaction Stoichiometry Problem Solving: Deducing the Limiting Reagent in Chemical Reactions
by: Chandrasegaran, Chandra, et al.
Published: (2009)

Effect of pulsed electrostatic fields on mass transfer in a modified Lewis cell
by: Assmann, Simon, et al.
Published: (2011)

Structural and Superconducting Property Variations with Nominal Mg Non-Stoichiometry in MgxB2 and Its Enhancement of Upper Critical Field
by: Chen, Soo Kien, et al.
Published: (2008)

Biodiesel production via homogeneous lewis acid catalyzed transesterification
by: Abd Rahman, Diyanti
Published: (2010)

Biodiesel production via homogeneous lewis acid catalyzed transesterification
by: Tio, Thiam Boon
Published: (2010)

The influence of students’ concept of mole, problem representation ability and mathematical ability on stoichiometry problem solving
by: Taha, Hafsah, et al.
Published: (2014)

Synthesis of NaAlH4/Al composites and their applications in hydrogen storage
by: Ianni, E., et al.
Published: (2018)

Crystal structure and in situ decomposition of Eu(BH4)2 and Sm(BH4)2
by: Humphries, Terry, et al.
Published: (2015)

Determination of Lewis and Brönsted acid sites by gas flow-injection technique
by: Musthofa, Malik, et al.
Published: (2010)

Integrative omics approaches for understanding the molecular pathogenesis of dementia with Lewy bodies
by: Goddard, Thomas R.
Published: (2025)

Impact of stoichiometry and strain on Ge1−x Sn x alloys from first principles calculations
by: O’Donnell, Conor, et al.
Published: (2021)

Effects of Non-Stoichiometry on Magnetic Properties and Microstructure of Ni₀.₃Zn₀.₇Fe₂ ±ₓO₄ and Mg₀.₅Zn₀.₅Fe₂ ±ₓO₄
by: Alias, Rosidah
Published: (2003)

Exploring the Archetypes of Initiation and Wise Old Man in C. S. Lewis’s The Chronicles of Narnia
by: Jafari, Bahereh Mehdizadeh
Published: (2010)

Synthesis and Characterisation of a Porous Al Scaffold Sintered from NaAlH4
by: Ianni, E., et al.
Published: (2017)

Complex transition metal hydrides incorporating ionic hydrogen: Synthesis and characterization of Na2Mg2FeH8 and Na2Mg2RuH8
by: Humphries, Terry, et al.
Published: (2015)

Wyndham Lewis’s ‘Very Bad Thing’: jazz, inter-war culture, and 'The Apes of God'
by: Waddell, Nathan
Published: (2013)

Genome-wide analysis of genetic correlation in dementia with Lewy bodies, Alzheimer’s and Parkinson’s diseases
by: Guerreiro, Rita, et al.
Published: (2016)

Optimisation of Design and Operation Parameters for Multicomponent Separation via Improved Lewis-Matheson Method
by: Ching Tiong, C., et al.
Published: (2017)

The Effects Of Science Writing Heuristic Approach To Improve Concept Understanding Of Stoichiometry And Attitude Towards Learning Chemistry Among Undergraduate Students
by: N. Pooranavelu, Kirupanithi
Published: (2018)

Recent advances in the 18-electron complex transition metal hydrides of Ni, Fe, Co and Ru
by: Humphries, Terry, et al.
Published: (2017)

Complex transition metal hydrides: Linear correlation of countercation electronegativity versus T-D bond lengths
by: Humphries, Terry, et al.
Published: (2015)

A New Evaluation: The Theological Influence of F. D. Maurice on the Imaginative Works of Lewis Carroll.
by: Gardiner, Karen
Published: (2023)