Lewis base complexes of AlH3: Prediction of preferred structure and stoichiometry

The structures adopted by a range of complexes AlH3·nL, (n = 1 or 2), have been explored in detail to identify the factors that determine the value of n, and whether a monomeric or dimeric arrangement is preferred for the 1 : 1 complexes. Single-crystal X-ray diffraction, vibrational and NMR spectro...

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Bibliographic Details
Main Authors: Humphries, Terry, Munroe, K., Decken, A., McGrady, G.
Format: Journal Article
Published: 2013
Online Access:http://hdl.handle.net/20.500.11937/4938