Direct determination of absolute configuration: a vibrational circular dichroism study on dimethyl-substituted phenyloxiranes synthesized by Shi epoxidation

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Direct determination of absolute configuration: a vibrational circular dichroism study on dimethyl-substituted phenyloxiranes synthesized by Shi epoxidation

The three possible dimethylsubstituted phenyloxiranes (cis, trans and geminal) were synthesized in both racemic (mCPBA) and enantiomerically enriched forms (Shi epoxidation) and subjected to a vibrational circular dichroism study. The experimental spectra were compared to theoretical spectra obtaine...

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Bibliographic Details
Main Authors:	Fristrup, P., Lassen, P., Tanner, D., Jalkanen, Karl
Format:	Journal Article
Published:	Springer Berlin 2008
Subjects:	DFT calculations Epoxidation Vibrational circular dichroism Absolute configuration Asymmetric catalysis
Online Access:	http://hdl.handle.net/20.500.11937/45018

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