Direct determination of absolute configuration: a vibrational circular dichroism study on dimethyl-substituted phenyloxiranes synthesized by Shi epoxidation
The three possible dimethylsubstituted phenyloxiranes (cis, trans and geminal) were synthesized in both racemic (mCPBA) and enantiomerically enriched forms (Shi epoxidation) and subjected to a vibrational circular dichroism study. The experimental spectra were compared to theoretical spectra obtaine...
| Main Authors: | , , , |
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| Format: | Journal Article |
| Published: |
Springer Berlin
2008
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| Subjects: | |
| Online Access: | http://hdl.handle.net/20.500.11937/45018 |