Syntheses of Pentanuclear Group 6 Iridium Clusters by Core Expansion of Tetranuclear Clusters with Ir(CO)2(η5-C5Me4R) (R = H, Me)

Mixed molybdenum/tungsten tetrairidium and dimolybdenum/ditungsten triiridium clusters were prepared in high yield by cluster-core expansion of molybdenum/tungsten triiridium and dimolybdenum/ditungsten diiridium precursors, respectively, and were analyzed by a combination of spectroscopic, structur...

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Bibliographic Details
Main Authors: Randles, M., Simpson, Peter, Gupta, V., Fu, J., Moxey, G., Schwich, T., Criddle, A., Petrie, S., MacLellan, J., Batten, S., Stranger, R., Cifuentes, M., Humphrey, M.
Format: Journal Article
Published: 2013
Online Access:http://hdl.handle.net/20.500.11937/37358