Supercritical Fluid Extraction of Black Pepper's Bioactive Compounds: Solubility and Mass Transfer

Mass transfer of black pepper’s bioactive compound extracted using supercritical CO2 was studied with the parameters such as range of temperature (45°–55°C), pressure (3,000–5,000 psi), CO2 flow rate (5–10 ml/min), and pepper particle size (0.4–1 mm). The solubility-controlled period and diffusion-c...

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Main Authors: Then, Siewping, Panau, Freddie, Samyudia, Yudi
Format: Book Chapter
Published: Springer 2013
Online Access:http://hdl.handle.net/20.500.11937/37299
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author Then, Siewping
Panau, Freddie
Samyudia, Yudi
author_facet Then, Siewping
Panau, Freddie
Samyudia, Yudi
author_sort Then, Siewping
building Curtin Institutional Repository
collection Online Access
description Mass transfer of black pepper’s bioactive compound extracted using supercritical CO2 was studied with the parameters such as range of temperature (45°–55°C), pressure (3,000–5,000 psi), CO2 flow rate (5–10 ml/min), and pepper particle size (0.4–1 mm). The solubility-controlled period and diffusion-controlled period of the extraction curve were examined. Static extraction was performed to calculate solubility, and the value obtained varied from 4.8 to 10.3 kg oil/m3 CO2. Transition time analyzed through extraction curve varied from 18 to 43 min and increased with particle size. Mass transfer rates for solubility-controlled period and diffusion-controlled period were analyzed. The average values were 2.7 × 10−3 kg/m3s and 1.04 × 10−4 kg/m3s, respectively. Particle size was found to be the dominant factor during solubility-controlled period, while pressure was the key factor for the intra-particle diffusion. The fluid-phase mass transfer coefficients and diffusivity were calculated based on Sovova’s model.
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institution Curtin University Malaysia
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spelling curtin-20.500.11937-372992017-09-13T13:38:13Z Supercritical Fluid Extraction of Black Pepper's Bioactive Compounds: Solubility and Mass Transfer Then, Siewping Panau, Freddie Samyudia, Yudi Mass transfer of black pepper’s bioactive compound extracted using supercritical CO2 was studied with the parameters such as range of temperature (45°–55°C), pressure (3,000–5,000 psi), CO2 flow rate (5–10 ml/min), and pepper particle size (0.4–1 mm). The solubility-controlled period and diffusion-controlled period of the extraction curve were examined. Static extraction was performed to calculate solubility, and the value obtained varied from 4.8 to 10.3 kg oil/m3 CO2. Transition time analyzed through extraction curve varied from 18 to 43 min and increased with particle size. Mass transfer rates for solubility-controlled period and diffusion-controlled period were analyzed. The average values were 2.7 × 10−3 kg/m3s and 1.04 × 10−4 kg/m3s, respectively. Particle size was found to be the dominant factor during solubility-controlled period, while pressure was the key factor for the intra-particle diffusion. The fluid-phase mass transfer coefficients and diffusivity were calculated based on Sovova’s model. 2013 Book Chapter http://hdl.handle.net/20.500.11937/37299 10.1007/978-1-4614-6208-8_32 Springer restricted
spellingShingle Then, Siewping
Panau, Freddie
Samyudia, Yudi
Supercritical Fluid Extraction of Black Pepper's Bioactive Compounds: Solubility and Mass Transfer
title Supercritical Fluid Extraction of Black Pepper's Bioactive Compounds: Solubility and Mass Transfer
title_full Supercritical Fluid Extraction of Black Pepper's Bioactive Compounds: Solubility and Mass Transfer
title_fullStr Supercritical Fluid Extraction of Black Pepper's Bioactive Compounds: Solubility and Mass Transfer
title_full_unstemmed Supercritical Fluid Extraction of Black Pepper's Bioactive Compounds: Solubility and Mass Transfer
title_short Supercritical Fluid Extraction of Black Pepper's Bioactive Compounds: Solubility and Mass Transfer
title_sort supercritical fluid extraction of black pepper's bioactive compounds: solubility and mass transfer
url http://hdl.handle.net/20.500.11937/37299