Lewis base complexes of AlH3: Structural determination of monomeric and polymeric adducts by X-ray crystallography and DFT calculations

The AlH3 adducts of TMEDA (Me2NCH2CH 2NMe2), DIOX (O(CH2CH2) 2O), TEA (Et3N), BDMA (PhNMe2), and TMPDA (Me2NCH2CH2CH2NMe2) have each been characterised by single-crystal X-ray diffraction at low temperature, by 1H, 14N and 27Al NMR and FT-Raman and FT-IR spectroscopy, and by DFT calculations and ele...

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Bibliographic Details
Main Authors: Humphries, Terry, Munroe, K., Decken, A., McGrady, G.
Format: Journal Article
Published: 2013
Online Access:http://hdl.handle.net/20.500.11937/35756