Diol-functionalised benzoates as novel linkers for the formation of coordination polymers

Diol-functionalised benzoates as novel linkers for the formation of coordination polymers

Reaction of La(HCO3)(3) with enantiomerically pure (R)-4-(2,3-dihydroxypropoxy) benzoic acid (DBAH) gives the neutral complex La(DBA)(3), which on heating undergoes self-organisation into a 1D coordination polymer, [La-2(DBA)(6)(H2O)(4)](infinity), as determined by X-ray crystallography.

Bibliographic Details
Main Authors: Andrews, P., Forsyth, C., Fraser, B., Junk, P., Massi, Massimiliano, Silberstein, Morry
Format: Journal Article
Published: The Royal Society of Chemistry 2007
Subjects:
Building-Blocks
Magnetic-Properties
Crystal-Structures
Metal-Organic Frameworks
Luminescent
Lanthanide Ions
Bridging Ligands
Solids
Carboxylates
Architectures
Online Access:http://hdl.handle.net/20.500.11937/35371

Internet

http://hdl.handle.net/20.500.11937/35371

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