Synthesis and characterisation of 3-vinyl[33](1,2,4) ferrocenophane

Treatment of [33](1,2,4)ferrocenophane (1) with N-methylformanilide and phosphorus oxychloride gave 3-formyl[33](1,2,4)ferrocenophane (2) in 96% yield. Subsequently, (2) was reacted with an ylid in THF and 3-vinyl[33](1,2,4)ferrocenophane (3) was obtained in 88% yield.

Bibliographic Details
Main Authors: Lu, J., Baker, M., Brown, David
Format: Journal Article
Published: Elsevier 2006
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/31060
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author Lu, J.
Baker, M.
Brown, David
author_facet Lu, J.
Baker, M.
Brown, David
author_sort Lu, J.
building Curtin Institutional Repository
collection Online Access
description Treatment of [33](1,2,4)ferrocenophane (1) with N-methylformanilide and phosphorus oxychloride gave 3-formyl[33](1,2,4)ferrocenophane (2) in 96% yield. Subsequently, (2) was reacted with an ylid in THF and 3-vinyl[33](1,2,4)ferrocenophane (3) was obtained in 88% yield.
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spelling curtin-20.500.11937-310602017-09-13T15:11:16Z Synthesis and characterisation of 3-vinyl[33](1,2,4) ferrocenophane Lu, J. Baker, M. Brown, David Ferrocenophane Bridged ferrocene Ferrocene Treatment of [33](1,2,4)ferrocenophane (1) with N-methylformanilide and phosphorus oxychloride gave 3-formyl[33](1,2,4)ferrocenophane (2) in 96% yield. Subsequently, (2) was reacted with an ylid in THF and 3-vinyl[33](1,2,4)ferrocenophane (3) was obtained in 88% yield. 2006 Journal Article http://hdl.handle.net/20.500.11937/31060 10.1016/j.ica.2005.11.017 Elsevier restricted
spellingShingle Ferrocenophane
Bridged ferrocene
Ferrocene
Lu, J.
Baker, M.
Brown, David
Synthesis and characterisation of 3-vinyl[33](1,2,4) ferrocenophane
title Synthesis and characterisation of 3-vinyl[33](1,2,4) ferrocenophane
title_full Synthesis and characterisation of 3-vinyl[33](1,2,4) ferrocenophane
title_fullStr Synthesis and characterisation of 3-vinyl[33](1,2,4) ferrocenophane
title_full_unstemmed Synthesis and characterisation of 3-vinyl[33](1,2,4) ferrocenophane
title_short Synthesis and characterisation of 3-vinyl[33](1,2,4) ferrocenophane
title_sort synthesis and characterisation of 3-vinyl[33](1,2,4) ferrocenophane
topic Ferrocenophane
Bridged ferrocene
Ferrocene
url http://hdl.handle.net/20.500.11937/31060