Negatively charged Ir(III) cyclometalated complexes containing a chelating bis-tetrazolato ligand: Synthesis, photophysics and the study of reactivity with electrophiles

Negatively charged Ir(III) cyclometalated complexes containing a chelating bis-tetrazolato ligand: Synthesis, photophysics and the study of reactivity with electrophiles

The bis-tetrazolate dianion [1,2 BTB]2−, which is the deprotonated form of 1,2 bis-(1H-tetrazol-5-yl)benzene [1,2-H2BTB], is for the first time exploited as an ancillary N^N ligand for negatively charged [Ir(C^N)2(N^N)]−-type complexes, where C^N is represented by cyclometalated 2-phenylpyridine (pp...

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Bibliographic Details
Main Authors: Fiorini, V., Zacchini, S., Raiteri, Paolo, Mazzoni, R., Zanotti, V., Massi, Massimiliano, Stagni, S.
Format: Journal Article
Published: R S C Publications 2016
Online Access:http://purl.org/au-research/grants/arc/FT130100033
http://hdl.handle.net/20.500.11937/30736

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