Negatively charged Ir(III) cyclometalated complexes containing a chelating bis-tetrazolato ligand: Synthesis, photophysics and the study of reactivity with electrophiles
The bis-tetrazolate dianion [1,2 BTB]2−, which is the deprotonated form of 1,2 bis-(1H-tetrazol-5-yl)benzene [1,2-H2BTB], is for the first time exploited as an ancillary N^N ligand for negatively charged [Ir(C^N)2(N^N)]−-type complexes, where C^N is represented by cyclometalated 2-phenylpyridine (pp...
| Main Authors: | , , , , , , |
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| Format: | Journal Article |
| Published: |
R S C Publications
2016
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| Online Access: | http://purl.org/au-research/grants/arc/FT130100033 http://hdl.handle.net/20.500.11937/30736 |