Experimental and Theoretical Characterization of 5,10-Diminoporphodimethenes: Dearomatized Porphyrinoids from Palladium-Catalyzed Hydrazinations of 5,10- Diarylporphyrins
A new dearomatized porphyrinoid, 5,10-diiminoporphodimethene (5,10-DIPD), has been prepared by palladium-catalyzed hydrazination of 5,10-dibromo-15,20-bis(3,5-di-tert-butylphenyl)porphyrin and its nickel(II) complex, by using ethyl and 4-methoxybenzyl carbazates. The oxidative dearomatization of the...
| Main Authors: | , , , , , |
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| Format: | Journal Article |
| Published: |
Wiley
2014
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| Online Access: | http://hdl.handle.net/20.500.11937/30187 |