Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes
Reaction of an excess of hydrated LnCl(3) (Ln = La, Gd, Ho, Yb, Y) with sodium 5-(2-pyridyl)tetrazolate (Napytz) in water led to the formation of either cationic disubstituted complexes (La, Gd, Ho) or neutral g-hydroxo-bridged dimers (Y, Yb). Interestingly, there is a lack of propensity for these d...
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| Format: | Journal Article |
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PERGAMON-ELSEVIER SCIENCE LTD
2007
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| Online Access: | http://hdl.handle.net/20.500.11937/29614 |
| _version_ | 1848752851827818496 |
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| author | Andrews, P. Beck, T. Fraser, B. Junk, Peter Massi, Massimiliano |
| author_facet | Andrews, P. Beck, T. Fraser, B. Junk, Peter Massi, Massimiliano |
| author_sort | Andrews, P. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Reaction of an excess of hydrated LnCl(3) (Ln = La, Gd, Ho, Yb, Y) with sodium 5-(2-pyridyl)tetrazolate (Napytz) in water led to the formation of either cationic disubstituted complexes (La, Gd, Ho) or neutral g-hydroxo-bridged dimers (Y, Yb). Interestingly, there is a lack of propensity for these disubstituted complexes to redistribute forming trisubstituted ones, which is a common behaviour in lanthanoid chemistry. Also, compared to their corresponding lanthanoid carboxylates, all these products are discrete molecular entities forming an extensive hydrogen-bonded and/or pi stacking network rather than hybrid polymeric frameworks. |
| first_indexed | 2025-11-14T08:15:12Z |
| format | Journal Article |
| id | curtin-20.500.11937-29614 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T08:15:12Z |
| publishDate | 2007 |
| publisher | PERGAMON-ELSEVIER SCIENCE LTD |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-296142017-09-13T15:27:37Z Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes Andrews, P. Beck, T. Fraser, B. Junk, Peter Massi, Massimiliano Ions Coordination Chemistry Metal-Organic Frameworks Tetrazolate Analogs Alpha-Amino-Acids Lanthanoid Chemistry Cluster Tetrazolate Complexes Metal Organic Frameworks Hydrogen-Bonded Networks Diagnostic-Tools Ligands Reaction of an excess of hydrated LnCl(3) (Ln = La, Gd, Ho, Yb, Y) with sodium 5-(2-pyridyl)tetrazolate (Napytz) in water led to the formation of either cationic disubstituted complexes (La, Gd, Ho) or neutral g-hydroxo-bridged dimers (Y, Yb). Interestingly, there is a lack of propensity for these disubstituted complexes to redistribute forming trisubstituted ones, which is a common behaviour in lanthanoid chemistry. Also, compared to their corresponding lanthanoid carboxylates, all these products are discrete molecular entities forming an extensive hydrogen-bonded and/or pi stacking network rather than hybrid polymeric frameworks. 2007 Journal Article http://hdl.handle.net/20.500.11937/29614 10.1016/j.poly.2007.08.017 PERGAMON-ELSEVIER SCIENCE LTD restricted |
| spellingShingle | Ions Coordination Chemistry Metal-Organic Frameworks Tetrazolate Analogs Alpha-Amino-Acids Lanthanoid Chemistry Cluster Tetrazolate Complexes Metal Organic Frameworks Hydrogen-Bonded Networks Diagnostic-Tools Ligands Andrews, P. Beck, T. Fraser, B. Junk, Peter Massi, Massimiliano Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes |
| title | Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes |
| title_full | Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes |
| title_fullStr | Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes |
| title_full_unstemmed | Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes |
| title_short | Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes |
| title_sort | synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (la, gd, ho, yb, y) bis 5-(2-pyridyl)tetrazolate complexes |
| topic | Ions Coordination Chemistry Metal-Organic Frameworks Tetrazolate Analogs Alpha-Amino-Acids Lanthanoid Chemistry Cluster Tetrazolate Complexes Metal Organic Frameworks Hydrogen-Bonded Networks Diagnostic-Tools Ligands |
| url | http://hdl.handle.net/20.500.11937/29614 |