Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes

Synthesis and structural characterisation of cationic, neutral and hydroxo-bridged lanthanoid (La, Gd, Ho, Yb, Y) bis 5-(2-pyridyl)tetrazolate complexes

Reaction of an excess of hydrated LnCl(3) (Ln = La, Gd, Ho, Yb, Y) with sodium 5-(2-pyridyl)tetrazolate (Napytz) in water led to the formation of either cationic disubstituted complexes (La, Gd, Ho) or neutral g-hydroxo-bridged dimers (Y, Yb). Interestingly, there is a lack of propensity for these d...

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Bibliographic Details
Main Authors: Andrews, P., Beck, T., Fraser, B., Junk, Peter, Massi, Massimiliano
Format: Journal Article
Published: PERGAMON-ELSEVIER SCIENCE LTD 2007
Subjects:
Ions
Coordination
Chemistry
Metal-Organic Frameworks
Tetrazolate
Analogs
Alpha-Amino-Acids
Lanthanoid Chemistry
Cluster
Tetrazolate Complexes
Metal Organic Frameworks
Hydrogen-Bonded Networks
Diagnostic-Tools
Ligands
Online Access:http://hdl.handle.net/20.500.11937/29614

Internet

http://hdl.handle.net/20.500.11937/29614

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