Photopolymerization of thiol-alkynes: Polysulfide networks

A series of photoinitiated reactions involving radical chain addition of dithiols across the triple bonds of dialkynes results in quantitative loss of all of the thiol and alkyne groups in 1:1 molar functional group neat mixtures. The reactions proceed rapidly to give uniform networks with relativel...

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Bibliographic Details
Main Authors: Chan, J., Zhou, H., Hoyle, C., Lowe, Andrew
Format: Journal Article
Published: American Chemical Society 2009
Online Access:http://hdl.handle.net/20.500.11937/29554