Cluster Control in Oligouranyl Complexes of p-t-Butylcalix[8]arene

Formation of uranyl ion complexes of p-t-butylcalix[8]arene by reaction of the calixarene with [UO2(dmso)5]2+ in the presence of various bases leads to the crystallisation of solids with interestingly different stoichiometry, involving both di- and tri-uranate oligomers bound to the calixarene in an...

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Bibliographic Details
Main Authors: Harrowfield, J., Ogden, Mark, Skelton, B., White, A.
Format: Journal Article
Published: The Royal Society of Chemistry 2010
Online Access:http://hdl.handle.net/20.500.11937/29459