Photoionization of Nb3CO and Nb3(CO)2: Is CO molecularly or dissociatively adsorbed on niobium?

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Photoionization of Nb3CO and Nb3(CO)2: Is CO molecularly or dissociatively adsorbed on niobium?

The photoionization efficiency spectra of gas-phase Nb3CO and Nb3(CO)2 have been acquired using a laser-ablation, photoionization mass spectrometer. The adiabatic ionization energies of the species are 5.82 ± 0.02 and 5.85 ± 0.02 eV, respectively, where error bars reflect precision; the values are a...

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Bibliographic Details
Main Authors:	Pedersen, D., Rayner, D., Simard, B., Addicoat, M., Buntine, Mark, Metha, G., Fielicke, A.
Format:	Journal Article
Published:	American Chemical Society 2004
Online Access:	http://hdl.handle.net/20.500.11937/27101

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