Photoionization of Nb3CO and Nb3(CO)2: Is CO molecularly or dissociatively adsorbed on niobium?
The photoionization efficiency spectra of gas-phase Nb3CO and Nb3(CO)2 have been acquired using a laser-ablation, photoionization mass spectrometer. The adiabatic ionization energies of the species are 5.82 ± 0.02 and 5.85 ± 0.02 eV, respectively, where error bars reflect precision; the values are a...
| Main Authors: | , , , , , , |
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| Format: | Journal Article |
| Published: |
American Chemical Society
2004
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| Online Access: | http://hdl.handle.net/20.500.11937/27101 |