Oxidation of iodide and iodine on birnessite (δ-MnO2) in the pH range 4-8

The oxidation of iodide by synthetic birnessite (δ-MnO2) was studied in perchlorate mediain the pH range 4-8. Iodine (I2) was detected as an oxidation product that was subsequently further oxidized to iodate (IO3). The third order rate constants, second order on iodide and first order on manganese o...

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Bibliographic Details
Main Authors: Allard, Sebastien, Von Gunten, Urs, Salhi, E., Nicolau, R., Gallard, H.
Format: Journal Article
Published: Elsevier Science Ltd 2009
Subjects:
Online Access:http://hdl.handle.net/20.500.11937/22471