A structural study of bis-(trimethylamine)alane, AlH3�2NMe3, by variable temperature X-ray crystallography and DFT calculations

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A structural study of bis-(trimethylamine)alane, AlH3�2NMe3, by variable temperature X-ray crystallography and DFT calculations

The structure of AlH3·2NMe3 has been investigated by single-crystal X-ray diffraction over the range of 296-173 K. Over this temperature range a phase change is observed from Cmca to Pbcm where the methyl groups convert from a statistically disordered conformation to adopt a mutually eclipsed confor...

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Bibliographic Details
Main Authors:	Humphries, Terry, Sirsch, P., Decken, A., Sean McGrady, G.
Format:	Journal Article
Published:	Elsevier 2009
Online Access:	http://hdl.handle.net/20.500.11937/19838

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