A structural study of bis-(trimethylamine)alane, AlH3�2NMe3, by variable temperature X-ray crystallography and DFT calculations
The structure of AlH3·2NMe3 has been investigated by single-crystal X-ray diffraction over the range of 296-173 K. Over this temperature range a phase change is observed from Cmca to Pbcm where the methyl groups convert from a statistically disordered conformation to adopt a mutually eclipsed confor...
| Main Authors: | , , , |
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| Format: | Journal Article |
| Published: |
Elsevier
2009
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| Online Access: | http://hdl.handle.net/20.500.11937/19838 |