Chloride substitution induced by mechano-chemical reactions between NaBH 4 and transition metal chlorides

Chloride substitution induced by mechano-chemical reactions between NaBH 4 and transition metal chlorides

Cl - to BH4- ion substitution was induced in NaBH 4 through mechano-chemical reactions with all the first period transition metal chlorides and CdCl 2. The products were identified by Rietveld refinement of powder X-ray and neutron diffraction data to be mainly Na(BH 4) 1-xCl x. These possess cubic...

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Bibliographic Details
Main Authors: Llamas-Jansa, I., Aliouane, N., Deledda, S., Fonnelop, J., Frommen, C., Humphries, Terry, Lieutenant, K., Sartori, S., Sorby, M., Hauback, B.
Format: Journal Article
Published: 2012
Online Access:http://hdl.handle.net/20.500.11937/17226

Internet

http://hdl.handle.net/20.500.11937/17226

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