One-step assembly of Re(I) tricarbonyl 2-pyridyltetrazolato metallacalix[3]arene with aqua emission and reversible three-electron oxidation
The reaction of 2-pyridyltetrazolate with [Re(CO)5X] (X = Cl, Br) yielded the formation of an unexpected cyclic metallacalix[3]-arene, as revealed by X-ray structural studies, characterised by aqua emission and reversible three-electron oxidation.
| Main Authors: | , , , , , , , , |
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| Format: | Journal Article |
| Published: |
The Royal Society of Chemistry
2013
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| Online Access: | http://hdl.handle.net/20.500.11937/15885 |