Functionalised beta-diketonate polynuclear lanthanoid hydroxo clusters: Synthesis, characterisation, and magnetic properties

Functionalised beta-diketonate polynuclear lanthanoid hydroxo clusters: Synthesis, characterisation, and magnetic properties

The controlled hydrolysis of lanthanoid trichloride hexahydrate (Ln = Nd, Eu, Ho) in methanol with the beta-diketone ligands dibenzoylmethane and 1,3-bis(4-ethoxyphenyl)propane-1,3-dione yielded tetranuclear and pentanuclear hydroxo clusters for Eu and Ho. In contrast, performing the reaction in the...

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Bibliographic Details
Main Authors: Andrews, P., Beck, T., Fraser, B., Junk, P., Massi, Massimiliano, Moubaraki, B., Murray, K., Silberstein, M.
Format: Journal Article
Published: PERGAMON-ELSEVIER SCIENCE LTD 2009
Subjects:
beta-Diketones
Crystal structures
Metal-hydroxo clusters
Magnetic susceptibility
Lanthanoids
Online Access:http://hdl.handle.net/20.500.11937/11219

Internet

http://hdl.handle.net/20.500.11937/11219

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