Templated assembly of a µ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate

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Templated assembly of a µ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate

Reaction of LaCl3 and dibenzoylmethane (Ph(2)acacH) in methanol with an excess of triethylamine resulted in the unexpected formation of a dodecanuclear hydroxo-bridged La cluster templated by CO32- and phenylglyoxylate (Phgly), as determined by X-ray crystallography.

Bibliographic Details
Main Authors:	Andrews, P., Beck, T., Forsyth, C., Fraser, B., Junk, P., Massi, Massimiliano, Roesky, P.
Format:	Journal Article
Published:	The Royal Society of Chemistry 2007
Subjects:	crystal-structures cubane clusters chemistry structural systematics cage basic nitrates coordination polymers Rare-earth complexes ions tetranuclear
Online Access:	http://hdl.handle.net/20.500.11937/10363

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