Templated assembly of a µ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate
Reaction of LaCl3 and dibenzoylmethane (Ph(2)acacH) in methanol with an excess of triethylamine resulted in the unexpected formation of a dodecanuclear hydroxo-bridged La cluster templated by CO32- and phenylglyoxylate (Phgly), as determined by X-ray crystallography.
| Main Authors: | , , , , , , |
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| Format: | Journal Article |
| Published: |
The Royal Society of Chemistry
2007
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| Subjects: | |
| Online Access: | http://hdl.handle.net/20.500.11937/10363 |