Templated assembly of a µ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate
Reaction of LaCl3 and dibenzoylmethane (Ph(2)acacH) in methanol with an excess of triethylamine resulted in the unexpected formation of a dodecanuclear hydroxo-bridged La cluster templated by CO32- and phenylglyoxylate (Phgly), as determined by X-ray crystallography.
| Main Authors: | , , , , , , |
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| Format: | Journal Article |
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The Royal Society of Chemistry
2007
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| Subjects: | |
| Online Access: | http://hdl.handle.net/20.500.11937/10363 |
| _version_ | 1848746212197400576 |
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| author | Andrews, P. Beck, T. Forsyth, C. Fraser, B. Junk, P. Massi, Massimiliano Roesky, P. |
| author_facet | Andrews, P. Beck, T. Forsyth, C. Fraser, B. Junk, P. Massi, Massimiliano Roesky, P. |
| author_sort | Andrews, P. |
| building | Curtin Institutional Repository |
| collection | Online Access |
| description | Reaction of LaCl3 and dibenzoylmethane (Ph(2)acacH) in methanol with an excess of triethylamine resulted in the unexpected formation of a dodecanuclear hydroxo-bridged La cluster templated by CO32- and phenylglyoxylate (Phgly), as determined by X-ray crystallography. |
| first_indexed | 2025-11-14T06:29:40Z |
| format | Journal Article |
| id | curtin-20.500.11937-10363 |
| institution | Curtin University Malaysia |
| institution_category | Local University |
| last_indexed | 2025-11-14T06:29:40Z |
| publishDate | 2007 |
| publisher | The Royal Society of Chemistry |
| recordtype | eprints |
| repository_type | Digital Repository |
| spelling | curtin-20.500.11937-103632017-09-13T14:48:43Z Templated assembly of a µ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate Andrews, P. Beck, T. Forsyth, C. Fraser, B. Junk, P. Massi, Massimiliano Roesky, P. crystal-structures cubane clusters chemistry structural systematics cage basic nitrates coordination polymers Rare-earth complexes ions tetranuclear Reaction of LaCl3 and dibenzoylmethane (Ph(2)acacH) in methanol with an excess of triethylamine resulted in the unexpected formation of a dodecanuclear hydroxo-bridged La cluster templated by CO32- and phenylglyoxylate (Phgly), as determined by X-ray crystallography. 2007 Journal Article http://hdl.handle.net/20.500.11937/10363 10.1039/b710534g The Royal Society of Chemistry restricted |
| spellingShingle | crystal-structures cubane clusters chemistry structural systematics cage basic nitrates coordination polymers Rare-earth complexes ions tetranuclear Andrews, P. Beck, T. Forsyth, C. Fraser, B. Junk, P. Massi, Massimiliano Roesky, P. Templated assembly of a µ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate |
| title | Templated assembly of a µ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate |
| title_full | Templated assembly of a µ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate |
| title_fullStr | Templated assembly of a µ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate |
| title_full_unstemmed | Templated assembly of a µ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate |
| title_short | Templated assembly of a µ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate |
| title_sort | templated assembly of a µ6-co32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate |
| topic | crystal-structures cubane clusters chemistry structural systematics cage basic nitrates coordination polymers Rare-earth complexes ions tetranuclear |
| url | http://hdl.handle.net/20.500.11937/10363 |