Templated assembly of a µ6-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate
Reaction of LaCl3 and dibenzoylmethane (Ph(2)acacH) in methanol with an excess of triethylamine resulted in the unexpected formation of a dodecanuclear hydroxo-bridged La cluster templated by CO32- and phenylglyoxylate (Phgly), as determined by X-ray crystallography.
Bibliographic Details
| Main Authors: |
Andrews, P.,
Beck, T.,
Forsyth, C.,
Fraser, B.,
Junk, P.,
Massi, Massimiliano,
Roesky, P. |
|---|
| Format: | Journal Article
|
|---|
| Published: |
The Royal Society of Chemistry
2007
|
|---|
| Subjects: | |
|---|
| Online Access: | http://hdl.handle.net/20.500.11937/10363
|
|---|