Phosphine, isocyanide, and alkyne reactivity at pentanuclear molybdenum/tungsten-iridium clusters

Phosphine, isocyanide, and alkyne reactivity at pentanuclear molybdenum/tungsten-iridium clusters

The trigonal bipyramidal clusters M2Ir3(μ-CO)3(CO)6(η5-C5H5)2(η5-C5Me4R) (M = Mo, R = Me 1a, R = H; M = W, R = Me, H) reacted with isocyanides to give ligand substitution products M2Ir3(μ-CO)3(CO)5(CNR′)(η5-C5H5)2(η5-C5Me4R) (M = Mo, R = Me, R′ = C6H3Me2-2,6 3a; M = Mo, R = Me, R′ = tBu 3b), in whic...

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Bibliographic Details
Main Authors: Simpson, Peter, Randles, M., Gupta, V., Fu, J., Moxey, G., Schwich, T., Morshedi, M., Cifuentes, M., Humphrey, M.
Format: Journal Article
Published: 2015
Online Access:http://hdl.handle.net/20.500.11937/10084

Internet

http://hdl.handle.net/20.500.11937/10084

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