Transesterification of Nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst

Biodiesel is an environmental friendly liquid fuel similar to conventional diesel in combustion properties. It has received international attention in recent times, as that biodiesel is renewable, non-toxic and safe to store. In this study, high grade biodiesel was produced from microalgae (Nannochl...

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Main Authors: Teo, Siow Hwa, Islam, Aminul, Yusaf, Talal, Yap, Taufiq Yun Hin
Format: Article
Language:English
Published: Elsevier 2014
Online Access:http://psasir.upm.edu.my/id/eprint/35887/
http://psasir.upm.edu.my/id/eprint/35887/
http://psasir.upm.edu.my/id/eprint/35887/
http://psasir.upm.edu.my/id/eprint/35887/1/Transesterification%20of%20Nannochloropsis%20oculata%20microalga%27s%20oil%20to%20biodiesel%20using%20calcium%20methoxide%20catalyst.pdf
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spelling upm-358872016-11-25T08:37:26Z http://psasir.upm.edu.my/id/eprint/35887/ Transesterification of Nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst Teo, Siow Hwa Islam, Aminul Yusaf, Talal Yap, Taufiq Yun Hin Biodiesel is an environmental friendly liquid fuel similar to conventional diesel in combustion properties. It has received international attention in recent times, as that biodiesel is renewable, non-toxic and safe to store. In this study, high grade biodiesel was produced from microalgae (Nannochloropsis oculata) derived lipids via transesterification reaction with methanol in the presence of heterogeneous Ca(OCH3)2 (calcium methoxide) catalyst. The biodiesel was produced with high yield; (92%) at 60 °C compared to the highest yield reported as 22% with the use of a Mg–Zr catalyst. The product exhibited excellent performances. The catalyst was characterized by TG/DTA (thermogravimetric-differential thermal analyses), XRD (X-ray diffraction), BET (Brunauer – Emmett – Teller), FTIR (Fourier transform infrared), SEM-EDX (scanning electron microscopy-energy dispersive spectrometer) and TEM (transmission electron microscopy) analysis. The effect of different reaction parameters including reaction time, methanol/oil molar ratio and catalyst dosage on the yield of FAME (fatty acid methyl ester) was studied. Interestingly, the catalyst can be reused five times successively without affecting the biodiesel yield. Biodiesel produced from microalgae oil consists of high levels of polyunsaturated fatty acids, making it highly suitable as winter grade biodiesel. Elsevier 2014-12-15 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/35887/1/Transesterification%20of%20Nannochloropsis%20oculata%20microalga%27s%20oil%20to%20biodiesel%20using%20calcium%20methoxide%20catalyst.pdf Teo, Siow Hwa and Islam, Aminul and Yusaf, Talal and Yap, Taufiq Yun Hin (2014) Transesterification of Nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst. Energy, 78. pp. 63-71. ISSN 0360-5442; ESSN: 1873-6785 http://www.sciencedirect.com/science/article/pii/S0360544214008676 10.1016/j.energy.2014.07.045
repository_type Digital Repository
institution_category Local University
institution Universiti Putra Malaysia
building UPM Institutional Repository
collection Online Access
language English
description Biodiesel is an environmental friendly liquid fuel similar to conventional diesel in combustion properties. It has received international attention in recent times, as that biodiesel is renewable, non-toxic and safe to store. In this study, high grade biodiesel was produced from microalgae (Nannochloropsis oculata) derived lipids via transesterification reaction with methanol in the presence of heterogeneous Ca(OCH3)2 (calcium methoxide) catalyst. The biodiesel was produced with high yield; (92%) at 60 °C compared to the highest yield reported as 22% with the use of a Mg–Zr catalyst. The product exhibited excellent performances. The catalyst was characterized by TG/DTA (thermogravimetric-differential thermal analyses), XRD (X-ray diffraction), BET (Brunauer – Emmett – Teller), FTIR (Fourier transform infrared), SEM-EDX (scanning electron microscopy-energy dispersive spectrometer) and TEM (transmission electron microscopy) analysis. The effect of different reaction parameters including reaction time, methanol/oil molar ratio and catalyst dosage on the yield of FAME (fatty acid methyl ester) was studied. Interestingly, the catalyst can be reused five times successively without affecting the biodiesel yield. Biodiesel produced from microalgae oil consists of high levels of polyunsaturated fatty acids, making it highly suitable as winter grade biodiesel.
format Article
author Teo, Siow Hwa
Islam, Aminul
Yusaf, Talal
Yap, Taufiq Yun Hin
spellingShingle Teo, Siow Hwa
Islam, Aminul
Yusaf, Talal
Yap, Taufiq Yun Hin
Transesterification of Nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst
author_facet Teo, Siow Hwa
Islam, Aminul
Yusaf, Talal
Yap, Taufiq Yun Hin
author_sort Teo, Siow Hwa
title Transesterification of Nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst
title_short Transesterification of Nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst
title_full Transesterification of Nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst
title_fullStr Transesterification of Nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst
title_full_unstemmed Transesterification of Nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst
title_sort transesterification of nannochloropsis oculata microalga's oil to biodiesel using calcium methoxide catalyst
publisher Elsevier
publishDate 2014
url http://psasir.upm.edu.my/id/eprint/35887/
http://psasir.upm.edu.my/id/eprint/35887/
http://psasir.upm.edu.my/id/eprint/35887/
http://psasir.upm.edu.my/id/eprint/35887/1/Transesterification%20of%20Nannochloropsis%20oculata%20microalga%27s%20oil%20to%20biodiesel%20using%20calcium%20methoxide%20catalyst.pdf
first_indexed 2018-09-07T16:26:20Z
last_indexed 2018-09-07T16:26:20Z
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