Lipase epoxidation optimizing of Jatropha curcas oil using perlauric acid

As a novel renewable resource, Jatropha curcas seed oil with an iodine value of 103.57g/100g, and containing almost 44.7% oleic acid, 32.8% linoleic acid as the dominant fatty acids, 13.78% palmitic acid, 6.92% stearic acid and 0.71% palmitoleic acid was epoxidized using hydrogen peroxide as oxy...

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Main Authors:	Rafiee Moghaddam, Roshanak, Salimon, Jumat, Haron, Md. Jelas, Jahangirian, Hossein, Ismail, Mohd. Halim Shah, Hosseini, Soraya, Rezayi, Majid
Format:	Article
Published:	Institute of Materials Physics 2014
Online Access:	http://psasir.upm.edu.my/id/eprint/34389/ http://psasir.upm.edu.my/id/eprint/34389/

id	upm-34389
recordtype	eprints
spelling	upm-343892015-12-15T00:19:25Z http://psasir.upm.edu.my/id/eprint/34389/ Lipase epoxidation optimizing of Jatropha curcas oil using perlauric acid Rafiee Moghaddam, Roshanak Salimon, Jumat Haron, Md. Jelas Jahangirian, Hossein Ismail, Mohd. Halim Shah Hosseini, Soraya Rezayi, Majid As a novel renewable resource, Jatropha curcas seed oil with an iodine value of 103.57g/100g, and containing almost 44.7% oleic acid, 32.8% linoleic acid as the dominant fatty acids, 13.78% palmitic acid, 6.92% stearic acid and 0.71% palmitoleic acid was epoxidized using hydrogen peroxide as oxygen donor and lauric acid as an active oxygen carrier in the presence of immobilized Candida antarctica Lipase B. In the present work the effects of variables (reaction temperature, enzyme load, the mole ratio of H2O2: C=C bonds, lauric acid load and reaction time) on the oxygen oxirane content (OOC) of epoxidized Jatropha curcas were investigated. The process was optimized for the enzymatic epoxidation of Jatropha oil, with the theoretical maximum OOC equal to 6.13%. The OOC of epoxidized Jatropha oil was 5.67% and a percentage relative conversion to oxirane(RCO) was 93.64 % under the following conditions:50C (temperature), 7% enzyme load (relative to the weight of Jatropha of oil), 3.5:1 mol ratio of H2O2: C=C bonds, 23% lauric acid load (relative to the weight of Jatropha oil) and 7.5 h (reaction time). Institute of Materials Physics 2014 Article PeerReviewed Rafiee Moghaddam, Roshanak and Salimon, Jumat and Haron, Md. Jelas and Jahangirian, Hossein and Ismail, Mohd. Halim Shah and Hosseini, Soraya and Rezayi, Majid (2014) Lipase epoxidation optimizing of Jatropha curcas oil using perlauric acid. Digest Journal of Nanomaterials and Biostructures, 9 (3). 1159-1169 . ISSN 1842 - 3582 http://www.chalcogen.ro/digest.html
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Putra Malaysia
building	UPM Institutional Repository
collection	Online Access
description	As a novel renewable resource, Jatropha curcas seed oil with an iodine value of 103.57g/100g, and containing almost 44.7% oleic acid, 32.8% linoleic acid as the dominant fatty acids, 13.78% palmitic acid, 6.92% stearic acid and 0.71% palmitoleic acid was epoxidized using hydrogen peroxide as oxygen donor and lauric acid as an active oxygen carrier in the presence of immobilized Candida antarctica Lipase B. In the present work the effects of variables (reaction temperature, enzyme load, the mole ratio of H2O2: C=C bonds, lauric acid load and reaction time) on the oxygen oxirane content (OOC) of epoxidized Jatropha curcas were investigated. The process was optimized for the enzymatic epoxidation of Jatropha oil, with the theoretical maximum OOC equal to 6.13%. The OOC of epoxidized Jatropha oil was 5.67% and a percentage relative conversion to oxirane(RCO) was 93.64 % under the following conditions:50C (temperature), 7% enzyme load (relative to the weight of Jatropha of oil), 3.5:1 mol ratio of H2O2: C=C bonds, 23% lauric acid load (relative to the weight of Jatropha oil) and 7.5 h (reaction time).
format	Article
author	Rafiee Moghaddam, Roshanak Salimon, Jumat Haron, Md. Jelas Jahangirian, Hossein Ismail, Mohd. Halim Shah Hosseini, Soraya Rezayi, Majid
spellingShingle	Rafiee Moghaddam, Roshanak Salimon, Jumat Haron, Md. Jelas Jahangirian, Hossein Ismail, Mohd. Halim Shah Hosseini, Soraya Rezayi, Majid Lipase epoxidation optimizing of Jatropha curcas oil using perlauric acid
author_facet	Rafiee Moghaddam, Roshanak Salimon, Jumat Haron, Md. Jelas Jahangirian, Hossein Ismail, Mohd. Halim Shah Hosseini, Soraya Rezayi, Majid
author_sort	Rafiee Moghaddam, Roshanak
title	Lipase epoxidation optimizing of Jatropha curcas oil using perlauric acid
title_short	Lipase epoxidation optimizing of Jatropha curcas oil using perlauric acid
title_full	Lipase epoxidation optimizing of Jatropha curcas oil using perlauric acid
title_fullStr	Lipase epoxidation optimizing of Jatropha curcas oil using perlauric acid
title_full_unstemmed	Lipase epoxidation optimizing of Jatropha curcas oil using perlauric acid
title_sort	lipase epoxidation optimizing of jatropha curcas oil using perlauric acid
publisher	Institute of Materials Physics
publishDate	2014
url	http://psasir.upm.edu.my/id/eprint/34389/ http://psasir.upm.edu.my/id/eprint/34389/
first_indexed	2018-09-07T16:12:46Z
last_indexed	2018-09-07T16:12:46Z
_version_	1610965861692080128

Lipase epoxidation optimizing of Jatropha curcas oil using perlauric acid

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