Theoretical insights into the enantioselectivity and mechanism of Diels-Alder reactions involving chiral cationic oxazaborolidinium catalyst
The chiral oxazaborolidinium ion catalyzed Diels-Alder reaction between 2-methyl-1,3-butadiene and 2,3-dimethyl-1,4-benzoquinone was studied by means of density functional theory (DFT) at the B3LYP/6-31G(d) level of theory. Different DFT-based theoretical approaches including the reaction force, the...
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| Published: |
2018
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| Online Access: | http://dspace.uniten.edu.my/jspui/handle/123456789/9793 |