Synthesis and characterization of transition metal complexes with aspirin thiourea ligands

The focus of this research is to react aspirin thiourea ligands with 3d transition metal (II) ion. There are two types of ligands that have been synthesized which are chloroaspirin with amine and chloroaspirin with amino acids. The ligands have been obtained by the condensation reaction between am...

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Main Author:	Enis Nadia, Binti Md. Yusof.
Format:	Project Report
Language:	English English
Published:	Universiti Malaysia Sarawak, (UNIMAS) 2011
Subjects:	GE Environmental Sciences QD Chemistry QH301 Biology
Online Access:	http://ir.unimas.my/6439/ http://ir.unimas.my/6439/1/Synthesis%20and%20characterization%20of%20transition%20metal%20complexes%20with%20aspirin%20thiourea%20ligand%2824%20pgs%29.pdf http://ir.unimas.my/6439/7/Synthesis%20and%20characterization%20of%20transition%20metal%20complexes%20with%20aspirin%20thiourea%20ligand%28OCR%29.pdf

id	unimas-6439
recordtype	eprints
spelling	unimas-64392015-05-25T06:31:15Z http://ir.unimas.my/6439/ Synthesis and characterization of transition metal complexes with aspirin thiourea ligands Enis Nadia, Binti Md. Yusof. GE Environmental Sciences QD Chemistry QH301 Biology The focus of this research is to react aspirin thiourea ligands with 3d transition metal (II) ion. There are two types of ligands that have been synthesized which are chloroaspirin with amine and chloroaspirin with amino acids. The ligands have been obtained by the condensation reaction between amine group and amino group. Then, transition metal complexes were synthesized by the direct reaction of 3d transition metal salts with aspirin thiourea ligands. Pure compounds of ligands and their metal complexes were characterized with FTIR, UVVisible, 1H NMR and 13C spectroscopy, and molar conductivity. All FTIR spectra of the ligands and transition metal complexes shows v(N-H), v(C=O) (carbonyl), v(C=O) (carboxylic), v(C=S), and v(C-N) absorption bands. The important 1H NMR chemical shift that were observed are δ(N1-H), δ(N2-H), δ(Ar-H), and δ(OH) chemical shift. Aspirin thiourea complexes were screened for their antibacterial activity using E. coli. 120 ppm is minimum inhibition concentration (MIC) values of the compounds 12 toward the bacteria were determined. Universiti Malaysia Sarawak, (UNIMAS) 2011 Project Report NonPeerReviewed text en http://ir.unimas.my/6439/1/Synthesis%20and%20characterization%20of%20transition%20metal%20complexes%20with%20aspirin%20thiourea%20ligand%2824%20pgs%29.pdf text en http://ir.unimas.my/6439/7/Synthesis%20and%20characterization%20of%20transition%20metal%20complexes%20with%20aspirin%20thiourea%20ligand%28OCR%29.pdf Enis Nadia, Binti Md. Yusof. (2011) Synthesis and characterization of transition metal complexes with aspirin thiourea ligands. [Project Report] (Unpublished)
repository_type	Digital Repository
institution_category	Local University
institution	Universiti Malaysia Sarawak
building	UNIMAS Institutional Repository
collection	Online Access
language	English English
topic	GE Environmental Sciences QD Chemistry QH301 Biology
spellingShingle	GE Environmental Sciences QD Chemistry QH301 Biology Enis Nadia, Binti Md. Yusof. Synthesis and characterization of transition metal complexes with aspirin thiourea ligands
description	The focus of this research is to react aspirin thiourea ligands with 3d transition metal (II) ion. There are two types of ligands that have been synthesized which are chloroaspirin with amine and chloroaspirin with amino acids. The ligands have been obtained by the condensation reaction between amine group and amino group. Then, transition metal complexes were synthesized by the direct reaction of 3d transition metal salts with aspirin thiourea ligands. Pure compounds of ligands and their metal complexes were characterized with FTIR, UVVisible, 1H NMR and 13C spectroscopy, and molar conductivity. All FTIR spectra of the ligands and transition metal complexes shows v(N-H), v(C=O) (carbonyl), v(C=O) (carboxylic), v(C=S), and v(C-N) absorption bands. The important 1H NMR chemical shift that were observed are δ(N1-H), δ(N2-H), δ(Ar-H), and δ(OH) chemical shift. Aspirin thiourea complexes were screened for their antibacterial activity using E. coli. 120 ppm is minimum inhibition concentration (MIC) values of the compounds 12 toward the bacteria were determined.
format	Project Report
author	Enis Nadia, Binti Md. Yusof.
author_facet	Enis Nadia, Binti Md. Yusof.
author_sort	Enis Nadia, Binti Md. Yusof.
title	Synthesis and characterization of transition metal complexes with aspirin thiourea ligands
title_short	Synthesis and characterization of transition metal complexes with aspirin thiourea ligands
title_full	Synthesis and characterization of transition metal complexes with aspirin thiourea ligands
title_fullStr	Synthesis and characterization of transition metal complexes with aspirin thiourea ligands
title_full_unstemmed	Synthesis and characterization of transition metal complexes with aspirin thiourea ligands
title_sort	synthesis and characterization of transition metal complexes with aspirin thiourea ligands
publisher	Universiti Malaysia Sarawak, (UNIMAS)
publishDate	2011
url	http://ir.unimas.my/6439/ http://ir.unimas.my/6439/1/Synthesis%20and%20characterization%20of%20transition%20metal%20complexes%20with%20aspirin%20thiourea%20ligand%2824%20pgs%29.pdf http://ir.unimas.my/6439/7/Synthesis%20and%20characterization%20of%20transition%20metal%20complexes%20with%20aspirin%20thiourea%20ligand%28OCR%29.pdf
first_indexed	2018-09-06T15:19:53Z
last_indexed	2018-09-06T15:19:53Z
_version_	1610871936883097600

Synthesis and characterization of transition metal complexes with aspirin thiourea ligands

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