Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands
Seven new organotin(IV) complexes (3-9) of pyruvic acid-4-ethyl-3-thiosemicarbazone (H2L1) (1) and 2- acetylpyridine-4-ethyl-3-thiosemicarbazone (HL) (2) have been synthesized and characterized by elemental analysis, molar conductivity, UV-Vis, FT-IR and 1H NMR spectral studies. The spectroscopic...
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unimas-61652015-09-22T02:23:27Z http://ir.unimas.my/6165/ Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands Adibah Amirah, Binti Abdul Nasir GE Environmental Sciences Q Science (General) Seven new organotin(IV) complexes (3-9) of pyruvic acid-4-ethyl-3-thiosemicarbazone (H2L1) (1) and 2- acetylpyridine-4-ethyl-3-thiosemicarbazone (HL) (2) have been synthesized and characterized by elemental analysis, molar conductivity, UV-Vis, FT-IR and 1H NMR spectral studies. The spectroscopic data indicate that all the organotin(IV) complexes (3-7) of the ligand [(H2L1) (1)], the ligand moiety COO‾ act as monodentate group, and coordinated to tin(IV) atom through carboxylato-O, azomethine-N, and thiolato-S atoms. Another organotin(IV) complexes (8-9) of the ligand [(HL) (2)], coordinated to tin (IV) atom through pyridine-N, azomethine-N, and thiolato-S atoms. Universiti Malaysia Sarawak, (UNIMAS) 2012 Project Report NonPeerReviewed text en http://ir.unimas.my/6165/1/Coordination%20chemistry%20of%20organotin%28IV%29%20complexes%20with%20substitute%20thiosemicarbazone%20ligands%2824pgs%29.pdf text en http://ir.unimas.my/6165/7/Coordination%20chemistry%20of%20organotin%28IV%29%20complexes%20with%20substitute%20thiosemicarbazone%20ligands%28OCR%29.pdf Adibah Amirah, Binti Abdul Nasir (2012) Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands. [Project Report] (Unpublished) |
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GE Environmental Sciences Q Science (General) Adibah Amirah, Binti Abdul Nasir Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands |
description |
Seven new organotin(IV) complexes (3-9) of pyruvic acid-4-ethyl-3-thiosemicarbazone (H2L1) (1) and 2-
acetylpyridine-4-ethyl-3-thiosemicarbazone (HL) (2) have been synthesized and characterized by elemental
analysis, molar conductivity, UV-Vis, FT-IR and 1H NMR spectral studies. The spectroscopic data indicate that all
the organotin(IV) complexes (3-7) of the ligand [(H2L1) (1)], the ligand moiety COO‾ act as monodentate group, and
coordinated to tin(IV) atom through carboxylato-O, azomethine-N, and thiolato-S atoms. Another organotin(IV)
complexes (8-9) of the ligand [(HL) (2)], coordinated to tin (IV) atom through pyridine-N, azomethine-N, and
thiolato-S atoms. |
format |
Project Report |
author |
Adibah Amirah, Binti Abdul Nasir |
author_facet |
Adibah Amirah, Binti Abdul Nasir |
author_sort |
Adibah Amirah, Binti Abdul Nasir |
title |
Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands |
title_short |
Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands |
title_full |
Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands |
title_fullStr |
Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands |
title_full_unstemmed |
Coordination chemistry of organotin(IV) complexes with substitute thiosemicarbazone ligands |
title_sort |
coordination chemistry of organotin(iv) complexes with substitute thiosemicarbazone ligands |
publisher |
Universiti Malaysia Sarawak, (UNIMAS) |
publishDate |
2012 |
url |
http://ir.unimas.my/6165/ http://ir.unimas.my/6165/1/Coordination%20chemistry%20of%20organotin%28IV%29%20complexes%20with%20substitute%20thiosemicarbazone%20ligands%2824pgs%29.pdf http://ir.unimas.my/6165/7/Coordination%20chemistry%20of%20organotin%28IV%29%20complexes%20with%20substitute%20thiosemicarbazone%20ligands%28OCR%29.pdf |
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2018-09-06T15:17:53Z |
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2018-09-06T15:17:53Z |
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1610871811413639168 |