Synthesis and characterization of organotin (IV) complexes of tridentate schiff bases containing -ono-donor atoms
Six o rganot in(IV) complexes of salicylaldehyde-carbohydrazone ligand (1) with RnSnC4_n (n = 1,2) have been synthesized in the presence of base and refluxing methanol in 1:2:1 molar ratio (metal:base:ligand). Two diorganotin(IV) complexes of salicylaldehyde-L-valine ligand (2) in 1:2: 1 molar rati...
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Universiti Malaysia Sarawak (UNIMAS)
2006
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unimas-182282017-10-23T03:41:04Z http://ir.unimas.my/18228/ Synthesis and characterization of organotin (IV) complexes of tridentate schiff bases containing -ono-donor atoms Foo, Irene Ping Ping. QD Chemistry Six o rganot in(IV) complexes of salicylaldehyde-carbohydrazone ligand (1) with RnSnC4_n (n = 1,2) have been synthesized in the presence of base and refluxing methanol in 1:2:1 molar ratio (metal:base:ligand). Two diorganotin(IV) complexes of salicylaldehyde-L-valine ligand (2) in 1:2: 1 molar ratio (metal:base:ligand) have also been synthesized with same method. All organotin(IV) complexes (3-10) have been characterized using CHN analysis, UV -Visible and IR spectral studies. All organotin(lV) complexes (3-10) are non electrolytic in nature. Spectral studies suggested that both the ligands (1-2) act as a dinegative tridentate nature in their organotin(IV) complexes. Therefore, a five coordinated molecular structure has been proposed for all the mentioned organotin(lV) complexes. Universiti Malaysia Sarawak (UNIMAS) 2006 Project Report NonPeerReviewed text en http://ir.unimas.my/18228/1/Synthesis%20and%20characterization%20of%20Organotin%20%28IV%29%20complexes%20of%20Tridentate%20Schiff.%20%2824%20pages%29.pdf text en http://ir.unimas.my/18228/2/Synthesis%20and%20characterization%20of%20Organotin%20%28IV%29%20complexes%20of%20Tridentate%20Schiff.%20%28fulltext%29.pdf Foo, Irene Ping Ping. (2006) Synthesis and characterization of organotin (IV) complexes of tridentate schiff bases containing -ono-donor atoms. [Project Report] (Unpublished) |
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QD Chemistry Foo, Irene Ping Ping. Synthesis and characterization of organotin (IV) complexes of tridentate schiff bases containing -ono-donor atoms |
description |
Six o rganot in(IV) complexes of salicylaldehyde-carbohydrazone ligand (1) with RnSnC4_n (n = 1,2) have been synthesized in the presence of base and refluxing methanol in 1:2:1 molar ratio (metal:base:ligand). Two diorganotin(IV) complexes of salicylaldehyde-L-valine ligand
(2) in 1:2: 1 molar ratio (metal:base:ligand) have also been synthesized with same method. All organotin(IV) complexes (3-10) have been characterized using CHN analysis, UV -Visible and IR spectral studies. All organotin(lV) complexes (3-10) are non electrolytic in nature. Spectral studies suggested that both the ligands (1-2) act as a dinegative tridentate nature in their organotin(IV) complexes. Therefore, a five coordinated molecular structure has been proposed for all the mentioned organotin(lV) complexes. |
format |
Project Report |
author |
Foo, Irene Ping Ping. |
author_facet |
Foo, Irene Ping Ping. |
author_sort |
Foo, Irene Ping Ping. |
title |
Synthesis and characterization of organotin (IV) complexes of tridentate schiff bases containing -ono-donor atoms |
title_short |
Synthesis and characterization of organotin (IV) complexes of tridentate schiff bases containing -ono-donor atoms |
title_full |
Synthesis and characterization of organotin (IV) complexes of tridentate schiff bases containing -ono-donor atoms |
title_fullStr |
Synthesis and characterization of organotin (IV) complexes of tridentate schiff bases containing -ono-donor atoms |
title_full_unstemmed |
Synthesis and characterization of organotin (IV) complexes of tridentate schiff bases containing -ono-donor atoms |
title_sort |
synthesis and characterization of organotin (iv) complexes of tridentate schiff bases containing -ono-donor atoms |
publisher |
Universiti Malaysia Sarawak (UNIMAS) |
publishDate |
2006 |
url |
http://ir.unimas.my/18228/ http://ir.unimas.my/18228/1/Synthesis%20and%20characterization%20of%20Organotin%20%28IV%29%20complexes%20of%20Tridentate%20Schiff.%20%2824%20pages%29.pdf http://ir.unimas.my/18228/2/Synthesis%20and%20characterization%20of%20Organotin%20%28IV%29%20complexes%20of%20Tridentate%20Schiff.%20%28fulltext%29.pdf |
first_indexed |
2018-09-06T16:42:15Z |
last_indexed |
2018-09-06T16:42:15Z |
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1610877119345197056 |