Synthesis, characterization and X-ray single crystal studies of mono-H-butyltin(IV) dichloride complex of pyruvic acid- 2-pyridylhydrazone [n-BuSnCl2(PAP)]

Mono-n-butyltin(IV) dichloride complex with the general formula [n-BuSnCl2(PAP)] has been synthesized by direct reaction of n-BuSnCl3 with pyruvic acid-2-pyridylhydrazone in the presence of KOH in equimolar ratio in absolute methanol under nitrogen atmosphere. Both, the ligand as well as the complex...

Full description

Bibliographic Details
Main Authors:	Affan, M.A., Shamsuddin, M., Hapipah, M.A., Fasihuddin, B.A., Foo, I.P.P.
Format:	Article
Published:	2009
Subjects:	QD Chemistry
Online Access:	http://www.scopus.com/inward/record.url?eid=2-s2.0-70350474481&partnerID=40&md5=3a2c03c11e4bb84586d6c176b49fe9a9 http://www.scopus.com/inward/record.url?eid=2-s2.0-70350474481&partnerID=40&md5=3a2c03c11e4bb84586d6c176b49fe9a9

id	um-5345
recordtype	eprints
spelling	um-53452013-04-04T01:37:20Z Synthesis, characterization and X-ray single crystal studies of mono-H-butyltin(IV) dichloride complex of pyruvic acid- 2-pyridylhydrazone [n-BuSnCl2(PAP)] Affan, M.A. Shamsuddin, M. Hapipah, M.A. Fasihuddin, B.A. Foo, I.P.P. QD Chemistry Mono-n-butyltin(IV) dichloride complex with the general formula [n-BuSnCl2(PAP)] has been synthesized by direct reaction of n-BuSnCl3 with pyruvic acid-2-pyridylhydrazone in the presence of KOH in equimolar ratio in absolute methanol under nitrogen atmosphere. Both, the ligand as well as the complex, have been characterized by elemental analyses, UV-visible, IR, 1H NMR spectral and X-ray diffraction studies. [n-BuSnCl2(PAP)] is nonelectrolytic in nature. Single crystal X-ray diffraction studies indicate that [n-BuSnCl2(PAP)], is six-coordinated and adopts a distorted octahedral configuration with the coordination via carboxylic-O2, imine-N and pyridyl-N atoms from the ligand. The crystal system of [n-BuSnCl2(PAP)] is tetragonal with space group I41,/a and the unit cell dimensions: a = 16.602(3)Å, b = 16.602(3)Å, c = 23.922(8)Å,α = β = γ =90°. 2009 Article PeerReviewed http://www.scopus.com/inward/record.url?eid=2-s2.0-70350474481&partnerID=40&md5=3a2c03c11e4bb84586d6c176b49fe9a9 Affan, M.A.; Shamsuddin, M.; Hapipah, M.A.; Fasihuddin, B.A.; Foo, I.P.P. (2009) Synthesis, characterization and X-ray single crystal studies of mono-H-butyltin(IV) dichloride complex of pyruvic acid- 2-pyridylhydrazone [n-BuSnCl2(PAP)]. Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry <http://eprints.um.edu.my/view/publication/Indian_Journal_of_Chemistry_-_Section_A_Inorganic,_Physical,_Theoretical_and_Analytical_Chemistry.html>, 48 (10). pp. 1388-1393. ISSN 03764710 http://eprints.um.edu.my/5345/
repository_type	Digital Repository
institution_category	Local University
institution	University Malaya
building	UM Research Repository
collection	Online Access
topic	QD Chemistry
spellingShingle	QD Chemistry Affan, M.A. Shamsuddin, M. Hapipah, M.A. Fasihuddin, B.A. Foo, I.P.P. Synthesis, characterization and X-ray single crystal studies of mono-H-butyltin(IV) dichloride complex of pyruvic acid- 2-pyridylhydrazone [n-BuSnCl2(PAP)]
description	Mono-n-butyltin(IV) dichloride complex with the general formula [n-BuSnCl2(PAP)] has been synthesized by direct reaction of n-BuSnCl3 with pyruvic acid-2-pyridylhydrazone in the presence of KOH in equimolar ratio in absolute methanol under nitrogen atmosphere. Both, the ligand as well as the complex, have been characterized by elemental analyses, UV-visible, IR, 1H NMR spectral and X-ray diffraction studies. [n-BuSnCl2(PAP)] is nonelectrolytic in nature. Single crystal X-ray diffraction studies indicate that [n-BuSnCl2(PAP)], is six-coordinated and adopts a distorted octahedral configuration with the coordination via carboxylic-O2, imine-N and pyridyl-N atoms from the ligand. The crystal system of [n-BuSnCl2(PAP)] is tetragonal with space group I41,/a and the unit cell dimensions: a = 16.602(3)Å, b = 16.602(3)Å, c = 23.922(8)Å,α = β = γ =90°.
format	Article
author	Affan, M.A. Shamsuddin, M. Hapipah, M.A. Fasihuddin, B.A. Foo, I.P.P.
author_facet	Affan, M.A. Shamsuddin, M. Hapipah, M.A. Fasihuddin, B.A. Foo, I.P.P.
author_sort	Affan, M.A.
title	Synthesis, characterization and X-ray single crystal studies of mono-H-butyltin(IV) dichloride complex of pyruvic acid- 2-pyridylhydrazone [n-BuSnCl2(PAP)]
title_short	Synthesis, characterization and X-ray single crystal studies of mono-H-butyltin(IV) dichloride complex of pyruvic acid- 2-pyridylhydrazone [n-BuSnCl2(PAP)]
title_full	Synthesis, characterization and X-ray single crystal studies of mono-H-butyltin(IV) dichloride complex of pyruvic acid- 2-pyridylhydrazone [n-BuSnCl2(PAP)]
title_fullStr	Synthesis, characterization and X-ray single crystal studies of mono-H-butyltin(IV) dichloride complex of pyruvic acid- 2-pyridylhydrazone [n-BuSnCl2(PAP)]
title_full_unstemmed	Synthesis, characterization and X-ray single crystal studies of mono-H-butyltin(IV) dichloride complex of pyruvic acid- 2-pyridylhydrazone [n-BuSnCl2(PAP)]
title_sort	synthesis, characterization and x-ray single crystal studies of mono-h-butyltin(iv) dichloride complex of pyruvic acid- 2-pyridylhydrazone [n-busncl2(pap)]
publishDate	2009
url	http://www.scopus.com/inward/record.url?eid=2-s2.0-70350474481&partnerID=40&md5=3a2c03c11e4bb84586d6c176b49fe9a9 http://www.scopus.com/inward/record.url?eid=2-s2.0-70350474481&partnerID=40&md5=3a2c03c11e4bb84586d6c176b49fe9a9
first_indexed	2018-09-05T16:51:29Z
last_indexed	2018-09-05T16:51:29Z
_version_	1610833646531379200

Synthesis, characterization and X-ray single crystal studies of mono-H-butyltin(IV) dichloride complex of pyruvic acid- 2-pyridylhydrazone [n-BuSnCl2(PAP)]

Similar Items