Halogen-bonded network of trinuclear copper(II) 4-iodopyrazolate complexes formed by mutual breakdown of chloroform and nanojars
Acidity created by the decomposition of chloroform solvent leads to breakdown of (Bu4N)2[{CuII(μ-OH)(μ-4-I-pz)}nCO3] (n = 27–31) nanojars in a chloroform/1,4-dioxane solution to the trinuclear complex (Bu4N)2[Cu3(μ 3-Cl)2(μ-4-I-pz)3Cl3]·0.5dioxane, which forms extended sheets based on C—I⋯Cl—Cu ha...
| Main Authors: | , |
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| Format: | Online |
| Language: | English |
| Published: |
International Union of Crystallography
2016
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095823/ |