The EIMS fragmentation mechanisms of the sesquiterpenes corvol ethers A and B, epi-cubebol and isodauc-8-en-11-ol

Farnesyl diphosphate (FPP) and all fifteen positional isomers of (13C1)FPP were enzymatically converted by the bacterial terpene cyclases corvol ether synthase from Kitasatospora setae, the epi-cubebol synthase from Streptosporangium roseum, and the isodauc-8-en-11-ol synthase from Streptomyces vene...

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Bibliographic Details
Main Authors: Rabe, Patrick, Dickschat, Jeroen S
Format: Online
Language:English
Published: Beilstein-Institut 2016
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4979868/