Reactivity studies of pincer bis-protic N-heterocyclic carbene complexes of platinum and palladium under basic conditions

Bis-protic N-heterocyclic carbene complexes of platinum and palladium (4) yield dimeric structures 6 when treated with sodium tert-butoxide in CH2Cl2. The use of a more polar solvent (THF) and a strong base (LiN(iPr)2) gave the lithium chloride adducts monobasic complex 7 or analogous dibasic comple...

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Bibliographic Details
Main Authors: Marelius, David C, Moore, Curtis E, Rheingold, Arnold L, Grotjahn, Douglas B
Format: Online
Language:English
Published: Beilstein-Institut 2016
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4979752/