The First Crystal Structure of a Reactive Dirhodium Carbene Complex and a Versatile Method for the Preparation of Gold Carbenes by Rhodium‐to‐Gold Transmetalation
The dirhodium carbene derived from bis(4‐methoxyphenyl)diazomethane and [Rh(tpa)4]⋅CH2Cl2 (tpa=triphenylacetate) was characterized by UV, IR, and NMR spectroscopy, HRMS, as well as by X‐ray diffraction. The isolated complex exhibits prototypical rhodium carbene reactivity in that it cyclopropanates...
| Main Authors: | , , |
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| Format: | Online |
| Language: | English |
| Published: |
WILEY‐VCH Verlag
2015
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4832834/ |