Active‐Metal Template Synthesis of a Halogen‐Bonding Rotaxane for Anion Recognition

The synthesis of an all‐halogen‐bonding rotaxane for anion recognition is achieved by using active‐metal templation. A flexible bis‐iodotriazole‐containing macrocycle is exploited for the metal‐directed rotaxane synthesis. Endotopic binding of a CuI template facilitates an active‐metal CuAAC iodotri...

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Bibliographic Details
Main Authors: Langton, Matthew J., Xiong, Yaoyao, Beer, Paul D.
Format: Online
Language:English
Published: WILEY‐VCH Verlag 2015
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4736451/