Self-instability of finite sized solid-liquid interfaces
In solid-liquid systems, macroscopic solids lose their equilibrium and melt in a manner that results in overall movement of the solid-liquid interface. This phenomenon occurs when they are subjected to temperature gradients or external stress, for example. However, many experiments suggest that the...
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Nature Publishing Group
2015
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4685266/ |
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pubmed-46852662015-12-30 Self-instability of finite sized solid-liquid interfaces Wu, L.K. Xu, B. Li, Q.L. Liu, W. Article In solid-liquid systems, macroscopic solids lose their equilibrium and melt in a manner that results in overall movement of the solid-liquid interface. This phenomenon occurs when they are subjected to temperature gradients or external stress, for example. However, many experiments suggest that the melting of nano- and micro-sized metallic nuclei follows a different process not described by traditional melting theory. In this paper, we demonstrate through simulation that the melting of solid nuclei of these sizes occurs via random breaches at the interfaces. Moreover, this breaching process occurs at the exact solid-liquid equilibrium temperature and in the absence of any external disturbance, which suggests the name “self-instability” for this melting process. We attribute this spontaneous instability to the curvature of the samples; based on the relationship between the sample’s instability and its curvature, we propose a destabilizing model for small systems. This model fits well with experimental results and leads to new insights into the instability behavior of small-sized systems; these insights have broad implications for research topics ranging from dendrite self-fragmentation to nanoparticle instability. Nature Publishing Group 2015-12-21 /pmc/articles/PMC4685266/ /pubmed/26685800 http://dx.doi.org/10.1038/srep18466 Text en Copyright © 2015, Macmillan Publishers Limited http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Wu, L.K. Xu, B. Li, Q.L. Liu, W. |
| spellingShingle |
Wu, L.K. Xu, B. Li, Q.L. Liu, W. Self-instability of finite sized solid-liquid interfaces |
| author_facet |
Wu, L.K. Xu, B. Li, Q.L. Liu, W. |
| author_sort |
Wu, L.K. |
| title |
Self-instability of finite sized solid-liquid interfaces |
| title_short |
Self-instability of finite sized solid-liquid interfaces |
| title_full |
Self-instability of finite sized solid-liquid interfaces |
| title_fullStr |
Self-instability of finite sized solid-liquid interfaces |
| title_full_unstemmed |
Self-instability of finite sized solid-liquid interfaces |
| title_sort |
self-instability of finite sized solid-liquid interfaces |
| description |
In solid-liquid systems, macroscopic solids lose their equilibrium and melt in a manner that results in overall movement of the solid-liquid interface. This phenomenon occurs when they are subjected to temperature gradients or external stress, for example. However, many experiments suggest that the melting of nano- and micro-sized metallic nuclei follows a different process not described by traditional melting theory. In this paper, we demonstrate through simulation that the melting of solid nuclei of these sizes occurs via random breaches at the interfaces. Moreover, this breaching process occurs at the exact solid-liquid equilibrium temperature and in the absence of any external disturbance, which suggests the name “self-instability” for this melting process. We attribute this spontaneous instability to the curvature of the samples; based on the relationship between the sample’s instability and its curvature, we propose a destabilizing model for small systems. This model fits well with experimental results and leads to new insights into the instability behavior of small-sized systems; these insights have broad implications for research topics ranging from dendrite self-fragmentation to nanoparticle instability. |
| publisher |
Nature Publishing Group |
| publishDate |
2015 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4685266/ |
| _version_ |
1613514784289849344 |