Yttrium Complexes of Arsine, Arsenide, and Arsinidene Ligands**
Deprotonation of the yttrium–arsine complex [Cp′3Y{As(H)2Mes}] (1) (Cp′=η5-C5H4Me, Mes=mesityl) by nBuLi produces the μ-arsenide complex [{Cp′2Y[μ-As(H)Mes]}3] (2). Deprotonation of the As–H bonds in 2 by nBuLi produces [Li(thf)4]2[{Cp′2Y(μ3-AsMes)}3Li], [Li(thf)4]2[3], in which the dianion 3 contai...
| Main Authors: | , , |
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| Format: | Online |
| Language: | English |
| Published: |
WILEY-VCH Verlag
2015
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4672686/ |