Crystal structures of 4-chloropyridine-2-carbonitrile and 6-chloropyridine-2-carbonitrile exhibit different intermolecular π-stacking, C—H⋯Nnitrile and C—H⋯Npyridine interactions
The crystal structures of two chlorocyanopyridines, namely 4-chloropyridine-2-carbonitrile and 6-chloropyridine-2-carbonitrile, exhibit unique intermolecular C—H⋯Nnitrile, C—H⋯Npyridine and offset face-to-face π-stacking interactions.
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International Union of Crystallography
2015
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| Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518955/ |
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pubmed-45189552015-08-14 Crystal structures of 4-chloropyridine-2-carbonitrile and 6-chloropyridine-2-carbonitrile exhibit different intermolecular π-stacking, C—H⋯Nnitrile and C—H⋯Npyridine interactions Montgomery, Matthew J. O’Connor, Thomas J. Tanski, Joseph M. Research Communications The crystal structures of two chlorocyanopyridines, namely 4-chloropyridine-2-carbonitrile and 6-chloropyridine-2-carbonitrile, exhibit unique intermolecular C—H⋯Nnitrile, C—H⋯Npyridine and offset face-to-face π-stacking interactions. International Union of Crystallography 2015-06-27 /pmc/articles/PMC4518955/ /pubmed/26279884 http://dx.doi.org/10.1107/S2056989015011767 Text en © Montgomery et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
| repository_type |
Open Access Journal |
| institution_category |
Foreign Institution |
| institution |
US National Center for Biotechnology Information |
| building |
NCBI PubMed |
| collection |
Online Access |
| language |
English |
| format |
Online |
| author |
Montgomery, Matthew J. O’Connor, Thomas J. Tanski, Joseph M. |
| spellingShingle |
Montgomery, Matthew J. O’Connor, Thomas J. Tanski, Joseph M. Crystal structures of 4-chloropyridine-2-carbonitrile and 6-chloropyridine-2-carbonitrile exhibit different intermolecular π-stacking, C—H⋯Nnitrile and C—H⋯Npyridine interactions |
| author_facet |
Montgomery, Matthew J. O’Connor, Thomas J. Tanski, Joseph M. |
| author_sort |
Montgomery, Matthew J. |
| title |
Crystal structures of 4-chloropyridine-2-carbonitrile and 6-chloropyridine-2-carbonitrile exhibit different intermolecular π-stacking, C—H⋯Nnitrile and C—H⋯Npyridine interactions |
| title_short |
Crystal structures of 4-chloropyridine-2-carbonitrile and 6-chloropyridine-2-carbonitrile exhibit different intermolecular π-stacking, C—H⋯Nnitrile and C—H⋯Npyridine interactions |
| title_full |
Crystal structures of 4-chloropyridine-2-carbonitrile and 6-chloropyridine-2-carbonitrile exhibit different intermolecular π-stacking, C—H⋯Nnitrile and C—H⋯Npyridine interactions |
| title_fullStr |
Crystal structures of 4-chloropyridine-2-carbonitrile and 6-chloropyridine-2-carbonitrile exhibit different intermolecular π-stacking, C—H⋯Nnitrile and C—H⋯Npyridine interactions |
| title_full_unstemmed |
Crystal structures of 4-chloropyridine-2-carbonitrile and 6-chloropyridine-2-carbonitrile exhibit different intermolecular π-stacking, C—H⋯Nnitrile and C—H⋯Npyridine interactions |
| title_sort |
crystal structures of 4-chloropyridine-2-carbonitrile and 6-chloropyridine-2-carbonitrile exhibit different intermolecular π-stacking, c—h⋯nnitrile and c—h⋯npyridine interactions |
| description |
The crystal structures of two chlorocyanopyridines, namely 4-chloropyridine-2-carbonitrile and 6-chloropyridine-2-carbonitrile, exhibit unique intermolecular C—H⋯Nnitrile, C—H⋯Npyridine and offset face-to-face π-stacking interactions. |
| publisher |
International Union of Crystallography |
| publishDate |
2015 |
| url |
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518955/ |
| _version_ |
1613253650931515392 |