Exploring the Use of a Guanine-Rich Catalytic DNA for Sulfoxide Preparation

A guanine-rich DNA oligonucleotide complexed with hemin was used to catalyze controlled oxygen transfer reactions to different sulfides for sulfoxide preparation in the presence of H2O2. Comparable activities were obtained when using fully modified L-DNA. In addition, oligonucleotide immobilization...

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Bibliographic Details
Main Authors: Dellafiore, María A., Montserrat, Javier M., Iribarren, Adolfo M.
Format: Online
Language:English
Published: Public Library of Science 2015
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4466802/