Self-assembly of heteroleptic dinuclear metallosupramolecular kites from multivalent ligands via social self-sorting
A Tröger's base-derived racemic bis(1,10-phenanthroline) ligand (rac)-1 and a bis(2,2'-bipyridine) ligand with a central 1,3-diethynylbenzene unit 2 were synthesized. Each of these ligands acts as a multivalent entity for the binding of two copper(I) ions. Upon coordination to the metal io...
Main Authors: | , |
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Format: | Online |
Language: | English |
Published: |
Beilstein-Institut
2015
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Online Access: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464459/ |