Tuning the size of a redox-active tetrathiafulvalene-based self-assembled ring

Tuning the size of a redox-active tetrathiafulvalene-based self-assembled ring

The synthesis of a new Pd coordination-driven self-assembled ring M6L3 constructed from a concave tetrapyridyl π-extended tetrathiafulvalene ligand (exTTF) is described. The same ligand is also able to self-assemble in a M4L2 mode as previously described. Herein, we demonstrate that the bulkiness of...

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Main Authors: Bivaud, Sébastien, Goeb, Sébastien, Croué, Vincent, Allain, Magali, Pop, Flavia, Sallé, Marc
Format: Online
Language:English
Published: Beilstein-Institut 2015
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464414/
id pubmed-4464414
recordtype oai_dc
spelling pubmed-44644142015-06-29 Tuning the size of a redox-active tetrathiafulvalene-based self-assembled ring Bivaud, Sébastien Goeb, Sébastien Croué, Vincent Allain, Magali Pop, Flavia Sallé, Marc Letter The synthesis of a new Pd coordination-driven self-assembled ring M6L3 constructed from a concave tetrapyridyl π-extended tetrathiafulvalene ligand (exTTF) is described. The same ligand is also able to self-assemble in a M4L2 mode as previously described. Herein, we demonstrate that the bulkiness of the ancillary groups in the Pd complex allows for modulating the size and the shape of the resulting discrete self-assembly, which therefore incorporate two (M4L2) or three (M6L3) electroactive exTTF sidewalls. Beilstein-Institut 2015-06-05 /pmc/articles/PMC4464414/ /pubmed/26124899 http://dx.doi.org/10.3762/bjoc.11.108 Text en Copyright © 2015, Bivaud et al; licensee Beilstein-Institut. http://www.beilstein-journals.org/bjoc This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc)
repository_type Open Access Journal
institution_category Foreign Institution
institution US National Center for Biotechnology Information
building NCBI PubMed
collection Online Access
language English
format Online
author Bivaud, Sébastien
Goeb, Sébastien
Croué, Vincent
Allain, Magali
Pop, Flavia
Sallé, Marc
spellingShingle Bivaud, Sébastien
Goeb, Sébastien
Croué, Vincent
Allain, Magali
Pop, Flavia
Sallé, Marc
Tuning the size of a redox-active tetrathiafulvalene-based self-assembled ring
author_facet Bivaud, Sébastien
Goeb, Sébastien
Croué, Vincent
Allain, Magali
Pop, Flavia
Sallé, Marc
author_sort Bivaud, Sébastien
title Tuning the size of a redox-active tetrathiafulvalene-based self-assembled ring
title_short Tuning the size of a redox-active tetrathiafulvalene-based self-assembled ring
title_full Tuning the size of a redox-active tetrathiafulvalene-based self-assembled ring
title_fullStr Tuning the size of a redox-active tetrathiafulvalene-based self-assembled ring
title_full_unstemmed Tuning the size of a redox-active tetrathiafulvalene-based self-assembled ring
title_sort tuning the size of a redox-active tetrathiafulvalene-based self-assembled ring
description The synthesis of a new Pd coordination-driven self-assembled ring M6L3 constructed from a concave tetrapyridyl π-extended tetrathiafulvalene ligand (exTTF) is described. The same ligand is also able to self-assemble in a M4L2 mode as previously described. Herein, we demonstrate that the bulkiness of the ancillary groups in the Pd complex allows for modulating the size and the shape of the resulting discrete self-assembly, which therefore incorporate two (M4L2) or three (M6L3) electroactive exTTF sidewalls.
publisher Beilstein-Institut
publishDate 2015
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4464414/
_version_ 1613234759936245760

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