Bisorption of chromium(VI) from aqueous solutions by Sargassum thunbergii Kuntze

The potential to remove Cr(VI) from aqueous solutions through biosorption using dried Sargassum thunbergii Kuntze was investigated with respect to initial pH, amount of biosorbent, initial Cr(VI) concentrations and temperature. Cr(VI) removal efficiency was influenced significantly by the variation...

Full description

Bibliographic Details
Main Authors: Wang, Yun, Li, Yingxia, Zhao, Feng Juan
Format: Online
Language:English
Published: Taylor & Francis 2014
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4434090/
id pubmed-4434090
recordtype oai_dc
spelling pubmed-44340902015-05-25 Bisorption of chromium(VI) from aqueous solutions by Sargassum thunbergii Kuntze Wang, Yun Li, Yingxia Zhao, Feng Juan Article; Agriculture and Environmental Biotechnology The potential to remove Cr(VI) from aqueous solutions through biosorption using dried Sargassum thunbergii Kuntze was investigated with respect to initial pH, amount of biosorbent, initial Cr(VI) concentrations and temperature. Cr(VI) removal efficiency was influenced significantly by the variation of pH, and the optimum pH was about 2.0. Moreover, the biosorption kinetics followed the pseudo-second-order model. The adsorption equilibrium was well described by the Langmuir and Freundlich isotherm models. The maximum adsorption capacity was 1.855 mmol/g at 318 K and pH 2.0. The adsorption processes were endothermic and the biosorption heat was 15.8 kJ/mol. Furthermore, the Fourier transform infrared spectroscopy suggested that amido-, hydroxyl-, C = O and C—O groups were involved in the biosorption of Cr(VI) onto S. thunbergii. Taylor & Francis 2014-03-04 2014-07-03 /pmc/articles/PMC4434090/ /pubmed/26019511 http://dx.doi.org/10.1080/13102818.2014.907028 Text en © 2014 The Author(s). Published by Taylor & Francis. http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/3.0/, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The moral rights of the named author(s) have been asserted.
repository_type Open Access Journal
institution_category Foreign Institution
institution US National Center for Biotechnology Information
building NCBI PubMed
collection Online Access
language English
format Online
author Wang, Yun
Li, Yingxia
Zhao, Feng Juan
spellingShingle Wang, Yun
Li, Yingxia
Zhao, Feng Juan
Bisorption of chromium(VI) from aqueous solutions by Sargassum thunbergii Kuntze
author_facet Wang, Yun
Li, Yingxia
Zhao, Feng Juan
author_sort Wang, Yun
title Bisorption of chromium(VI) from aqueous solutions by Sargassum thunbergii Kuntze
title_short Bisorption of chromium(VI) from aqueous solutions by Sargassum thunbergii Kuntze
title_full Bisorption of chromium(VI) from aqueous solutions by Sargassum thunbergii Kuntze
title_fullStr Bisorption of chromium(VI) from aqueous solutions by Sargassum thunbergii Kuntze
title_full_unstemmed Bisorption of chromium(VI) from aqueous solutions by Sargassum thunbergii Kuntze
title_sort bisorption of chromium(vi) from aqueous solutions by sargassum thunbergii kuntze
description The potential to remove Cr(VI) from aqueous solutions through biosorption using dried Sargassum thunbergii Kuntze was investigated with respect to initial pH, amount of biosorbent, initial Cr(VI) concentrations and temperature. Cr(VI) removal efficiency was influenced significantly by the variation of pH, and the optimum pH was about 2.0. Moreover, the biosorption kinetics followed the pseudo-second-order model. The adsorption equilibrium was well described by the Langmuir and Freundlich isotherm models. The maximum adsorption capacity was 1.855 mmol/g at 318 K and pH 2.0. The adsorption processes were endothermic and the biosorption heat was 15.8 kJ/mol. Furthermore, the Fourier transform infrared spectroscopy suggested that amido-, hydroxyl-, C = O and C—O groups were involved in the biosorption of Cr(VI) onto S. thunbergii.
publisher Taylor & Francis
publishDate 2014
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4434090/
_version_ 1613224356419207168