Halogen- and Hydrogen-Bonded Salts and Co-crystals Formed from 4-Halo-2,3,5,6-tetrafluorophenol and Cyclic Secondary and Tertiary Amines: Orthogonal and Non-orthogonal Halogen and Hydrogen Bonding, and Synthetic Analogues of Halogen-Bonded Biological Systems

Co-crystallisation of, in particular, 4-iodotetrafluorophenol with a series of secondary and tertiary cyclic amines results in deprotonation of the phenol and formation of the corresponding ammonium phenate. Careful examination of the X-ray single-crystal structures shows that the phenate anion deve...

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Bibliographic Details
Main Authors: Takemura, Akihiro, McAllister, Linda J, Hart, Sam, Pridmore, Natalie E, Karadakov, Peter B, Whitwood, Adrian C, Bruce, Duncan W
Format: Online
Language:English
Published: WILEY-VCH Verlag 2014
Online Access:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4324131/